Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Carrier Transport01:21

Carrier Transport

622
The generation of electrical current in semiconductors is fundamentally driven by two mechanisms: drift and diffusion. These processes are essential for the functionality and performance of semiconductor-based devices.
Drift Current:
The drift of charge carriers is started by an external electric field (E). Charged particles, such as electrons and holes, experience an acceleration between collisions with lattice atoms. For electrons, this results in a drift velocity (vd) given by:
622
Colors and Magnetism03:02

Colors and Magnetism

12.4K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
12.4K
Magnetic Moment of an Electron01:23

Magnetic Moment of an Electron

1.9K
Electrons revolving around a nucleus are analogous to a circular current carrying loop. This current produces a magnetic dipole moment proportional to the electron's orbital angular momentum. Since the orbital angular momentum is quantized in terms of the reduced Planck's constant, the dipole moment is quantized in the Bohr Magneton. The value of the Bohr magneton is 9.27 x 10-24 Am2. Electrons also have an intrinsic spin angular momentum, and the associated spin magnetic moment is...
1.9K
Electron Behavior00:54

Electron Behavior

105.2K
Overview
Electrons are negatively charged subatomic particles that are attracted to an orbit around the positively-charged nucleus of an atom. They reside in locations that are associated with energy levels called shells and are further organized into sub-shells and orbitals within each shell.
Electrons Orbit the Nucleus
Electrons are found in specific locations outside of the nucleus. The shell in which an electron resides indicates the general energy level of the electron: those closer to the...
105.2K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

24.6K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
24.6K
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

1.5K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.5K

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Advancing Reproducibility and Open Data in Theoretical and Computational Chemistry.

Journal of chemical theory and computation·2026
Same author

Exciton dissociation from non-adiabatic molecular dynamics: The role of initial conditions, dimensionality, and disorder.

The Journal of chemical physics·2026
Same author

Cation Site Occupancy in Natural Ferroan Double Carbonates via Mössbauer and Fe K-Edge X-ray Absorption Spectroscopy.

Inorganic chemistry·2026
Same author

Fingerprinting Uranium Oxides with Electron Energy Loss Spectroscopy Supported by Theoretical Computations.

The journal of physical chemistry. A·2026
Same author

Transition from Vehicular to Structural Ionic Transport in Electrified Alkali Aqueous Solutions.

The journal of physical chemistry. B·2026
Same author

Libration of hydroxyl groups in layered aluminum (oxy)hydroxides and other material analogs: insights from inelastic neutron scattering and theory.

Physical chemistry chemical physics : PCCP·2026

関連する実験動画

Updated: Oct 1, 2025

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

3.3K

スピン制限密度関数理論による大量ヘマタイトにおける電子と穴の移動

Christian S Ahart1, Kevin M Rosso2, Jochen Blumberger1

  • 1Department of Physics and Astronomy, University College London, London WC1E 6BT, U.K.

Journal of the American Chemical Society
|March 3, 2022
PubMed
まとめ

ヘマタイト (α-Fe2O3) の穴は局所的なポラロンを形成し,緩やかな輸送を引き起こし,電子は2つの場所に移動し,光電気化学的な水分裂を高速に可能にします.

科学分野:

  • 材料科学
  • 物理化学
  • コンピュータ化学

背景:

  • 移行金属酸化物は,光電気化学的な水分解に不可欠です.
  • これらの材料の電荷载体輸送を理解することは,効率を向上させるための鍵です.
  • ヘマタイト (α-Fe2O3) は水分裂のための広く研究された材料ですが,その電荷輸送機構は完全に理解されていません.

研究 の 目的:

  • ヘマタイトの穴と過剰な電子の性質と輸送メカニズムを調査する.
  • 緩やかな電荷運搬の原点を解明する
  • 光触媒活動を強化するための基本的な洞察を提供すること.

主な方法:

  • 周期,スピン制約,ギャップ最適化ハイブリッド密度関数理論の計算.
  • 物質の原子構造の電荷キャリアの位置と歪みの分析.
  • 充電輸送のための活性化エネルギーと移動性の計算.

主要な成果:

  • ヘマタイトの穴は,周囲のFe-O結合の四角歪みにより,単一の鉄原子にポラロンとして位置する.
  • このポラロン局所化は,0.031cm2/{Vs}の穴の移動性を有する遅いジャンプ輸送につながります.
  • 余剰の電子は隣接する2つのFe単位に移動し,その結果,電子の移動性が0.098cm2/{Vs}で,穴の約3倍になります.

さらに関連する動画

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
06:53

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

Published on: June 9, 2023

2.1K
Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
16:11

Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry

Published on: June 8, 2022

2.4K

関連する実験動画

Last Updated: Oct 1, 2025

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

3.3K
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
06:53

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

Published on: June 9, 2023

2.1K
Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
16:11

Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry

Published on: June 8, 2022

2.4K

結論:

  • 穴と電子の独特の局所化は,ヘマタイトの輸送特性に大きな影響を与える.
  • 電子の移転とそれに関連するより大きな空間的移動は,電荷輸送の効率を高めます.
  • これらの発見は,効率的な光電気化学的水分解のための血岩の最適化に重要な洞察を提供します.