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Updated: Sep 28, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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不飽和のCriegee中間体における急速なアリル1,6H原子移転

Anne S Hansen1, Yujie Qian1, Christopher A Sojdak1

  • 1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323 United States.

Journal of the American Chemical Society
|March 28, 2022
PubMed
まとめ

2-ブテナル酸化物 クリーギーの中間物質の新しいメカニズムは,赤外線で活性化された1,6水素原子移転によって,ヒドロキシル (OH) ラジカルを素早く形成する. この経路は,形状の変化とトンネルの形成を伴うもので,熱帯圏でのOH産生を高めます.

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