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Updated: Sep 24, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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リバーシブル・フォスフィニデン・トランスファーにおける構造スナップショット:SnP二重結合の合成,構造,および反応化学

Malte Fischer1, Matthew M D Roy2, Lewis L Wales1

  • 1Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, U.K.

Journal of the American Chemical Society
|May 10, 2022
PubMed
まとめ

研究者は,アミド置換スタニレンとフォスファ-ウィティッグ反応剤を反応させ,新しいPドナー安定スタニレンを合成した. ステリックチューニングにより,フォスフィニデンの転移が可能になり,極性SnP二重結合を持つスタナフォスフェンが形成された.

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