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Updated: Sep 24, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

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単核非ヘム鉄複合体におけるラジカルハロゲン化と水酸化を駆動する要因は? 実験と計算を組み合わせた研究

Emilie F Gérard1,2, Vishal Yadav3, David P Goldberg3

  • 1Manchester Institute of Biotechnology, The University of Manchester, 131 Princess Street, Manchester M1 7DN, United Kingdom.

Journal of the American Chemical Society
|May 10, 2022
PubMed
まとめ

非ヘム鉄ハロゲネーゼは,二次炭素基に選択的にハロゲン (X•) を転送し,反応がエンダーゴニックである三次炭素基とは違います. この選択性は熱力学的安定性と二次的調整球効果によって支配される.

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