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Updated: Sep 23, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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ダイアジリンを用いた生物触媒カルベンの移転

Nicholas J Porter1, Emma Danelius2,3, Tamir Gonen2,3,4

  • 1Division of Chemistry and Chemical Engineering, Division of Biology and Bioengineering, California Institute of Technology, 1200 East California Boulevard, MC 210-41, Pasadena, California 91125, United States.

Journal of the American Chemical Society
|May 13, 2022
PubMed
まとめ

研究者は,安定したディアジリンから生物触媒カルベンの移転のためにAeropyrum pernix protoglobin (ApePgb) の変種を設計した. この画期的な発見により 室温でのカルベンの前駆物質を用いた 新しい合成方法が可能になりました

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