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酸化MHAT触媒で推論された塩塩基基コバルト ((IV) アルキル複合体におけるコバルト-炭素結合

Conner V Wilson1, Dongyoung Kim1, Ajay Sharma2

  • 1Department of Chemistry, Yale University, New Haven, Connecticut 06520, United States.

Journal of the American Chemical Society
|June 3, 2022
PubMed
まとめ

この研究は,金属水素原子移転 (MHAT) 触媒における重要なコバルト (IV) 中間物質を特徴づけている. 発見は,逆極性を持つ異常なコバルト-炭素結合を明らかにし,ステリカルに阻害されたアルケンのより穏やかな機能化を可能にします.

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