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Updated: Sep 20, 2025

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

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デカルボキシラティブ・クロスカップリングによるNi-カタライズドエナチオセレクティブ・ダイアルキルカルビノール合成:開発,範囲,および応用

Yang Gao1, Benxiang Zhang1, Laura Levy1

  • 1Department of Chemistry, Scripps Research, 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

Journal of the American Chemical Society
|June 7, 2022
PubMed
まとめ

研究者らは,第1回レドックス活性エステル (RAE) を使用したネギシ型脱炭化アルキレーションを開発した. この根基ベースの方法は,エナチオピュアなダイアルキルカルビノールの合成を簡素化します.

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