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選択的同位体ラベリングとLC-フォト-CIDNPは,低ナノモラー濃度でのNMRスペクトロシーを可能にします

Hanming Yang1, Siyu Li1, Clayton A Mickles1

  • 1Department of Chemistry, University of Wisconsin─Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|June 14, 2022
PubMed
まとめ

核磁気共振 (NMR) のスペクトロスコピーの感度は,低濃度光化学的に誘発されたダイナミックな核極化 (LC-photo-CIDNP) を使用して強化されます. スピンで希釈されたトリプトファンの同位体は,希釈されたサンプルを検出するためにLC-フォト-CIDNPのハイパーポラライゼーションを著しく強化します.

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