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Updated: Sep 7, 2025

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

Published on: July 14, 2015

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自己加速P-C結合反応による超ミクロポラスの有機リンポリマー:クロスリンク環境と多孔構造に対する運動効果

Zhikai Zhang1, Qing Wang1, Haiming Liu1

  • 1School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, People's Republic of China.

Journal of the American Chemical Society
|June 23, 2022
PubMed
まとめ

研究者らは,新しいリンと炭素の結合反応を用いて,多孔性有機リンポリマー (POPP) を開発した. この方法により,高表面積と制御された超微孔性が得られ,CO2の捕獲能力が向上します.

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Anionic Chain-Growth Polymerization: Overview

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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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