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Updated: Sep 6, 2025

Separation of Aldehydes and Reactive Ketones from Mixtures Using a Bisulfite Extraction Protocol
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カルボニル化合物の硫黄イリドによる直接的ステレオダイバーゲントオレフィネーション

Jérémy Merad1, Phillip S Grant1, Tobias Stopka1

  • 1Institute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.

Journal of the American Chemical Society
|June 30, 2022
PubMed
まとめ

この研究は,カルボニルオレフィネーションのための新しい反応剤としてチオロニウムイリドを導入し,確立された有機化学の原則に異議を唱える. この方法は,アルデヒドからZアルケンの立体選択合成と,N-トシリミンからEアルケンの合成を実現する.

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