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Updated: Sep 4, 2025

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[Fe4S4]クラスターにおける鉄と硫黄の間の可逆アルキル群移動

Mengshan Ye1, Alexandra C Brown1, Daniel L M Suess1

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|July 13, 2022
PubMed
まとめ

合成鉄硫黄のクラスターは,有機的ラジカルを放出し,ラジカルS-アデノシル-l-メチオニン (SAM) 酵素を模倣する. 研究者はアルキル群が鉄から硫黄に移動する重要な中間物質を特定し,メタロ酵素触媒の洞察を明らかにしました.

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Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
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