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Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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ダイアステロセレクティブのラジカル1,4-エステル移行: SmI2とアサイクリックエステルのラジカルサイクリング

Charlotte Morrill1, Áron Péter1, Ilma Amalina1

  • 1Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, U.K.

Journal of the American Chemical Society
|July 20, 2022
PubMed
まとめ

この研究は,サマリウム (II) ディオイド (SmI2) 媒介によるアサイクリックエステルの新しい還元サイクルを導入する. この前例のない反応により,ステレオ定義されたアルケンの炭水化化合物合成が可能です.

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