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Updated: Sep 2, 2025

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
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Pdベースのダイオトロプ的再配列によって可能になった飽和アミドの移動性カルボフッ素化

Guoqiang Yang1, Hua Wu1,2, Simone Gallarati3

  • 1Laboratory of Synthesis and Natural Products (LSPN), Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, EPFL-SB-ISIC-LSPN, BCH5304, CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|August 2, 2022
PubMed
まとめ

この研究は,アサイクリック分子における四次炭素を改変するための新しいパラジウム触媒反応を導入する. この方法は,アミドの移動性カルボフッ化を実現し,有価なフッ化化合物の合成を可能にします.

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