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Updated: Aug 30, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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(+) -ムチリンの総合成:環状 [2+2] サイクル添加/断片化アプローチ

Han Chen1, Zesheng Li1, Peng Shao2

  • 1Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education and Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

Journal of the American Chemical Society
|August 31, 2022
PubMed
まとめ

この研究は,天然産物 (+) - ムチリンの新種のエナンチオセレクティブ・トータル合成を提示する. 鍵となるステップは,クライゼン再配置と [2+2] 光回路加法で,ユニークなプロペラン骨格を構築することでした.

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