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Updated: Aug 29, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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断片化へのダイナミックな傾向にもかかわらず,ディロジウムテトラカルボキシラート触媒反応にC-H挿入:反応効率と触媒設計への影響

Wentao Guo1, Stephanie R Hare1, Shu-Sen Chen1

  • 1Department of Chemistry, University of California, Davis, California 95616, United States.

Journal of the American Chemical Society
|September 13, 2022
PubMed
まとめ

Rh触媒によるC-H挿入反応は複数の産物を生成する. Ab initio分子ダイナミクスシミュレーションは,特により大きな空洞と特定の置換剤を使用する触媒設計が,望ましいβ-ラクトンに対する選択性を制御する方法を明らかにします.

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