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A Direct, Early Stage Guanidinylation Protocol for the Synthesis of Complex Aminoguanidine-containing Natural Products
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ユズリン型アルカロイドダフグラシリンの総合成

Li-Xuan Li1,2, Long Min1, Tian-Bing Yao1

  • 1Shenzhen Grubbs Institute, Department of Chemistry, Guangdong Provincial Key Laboratory of Catalytic Chemistry, Southern University of Science and Technology, Shenzhen 518055, China.

Journal of the American Chemical Society
|October 5, 2022
PubMed
まとめ

ユズリンのような複雑なアルカロイドであるダフグラシリンの最初の完全な合成が達成されました. この突破は新しいサイクル添加と再配置反応を用いて 独特のブリッジリングシステムを構築しました

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