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Updated: Aug 25, 2025

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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ディシハーボルA,C,Dのエナンチオセレクティブ・トータル合成

Shengkun Hu1, Yefeng Tang2

  • 1Department of Chemistry, Tsinghua University, Beijing 100084, China.

Journal of the American Chemical Society
|October 13, 2022
PubMed
まとめ

この研究では,独特のセスキートルペンであるダイヒルボールA,C,Dのエナント選択的全合成を詳細に説明しています. 主要な合成ステップは,光誘発のサイクル添加とアニオン再配列であり,ダイハーボルCとDの改訂された構造につながります.

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