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Updated: Aug 25, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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アップストリームレドックス酵素のリサイクリングは,シュードアスピドスペルマアルカロイド生物合成におけるサイクロアディションの地域選択性を拡大する

Mohamed O Kamileen1,2, Matthew D DeMars1, Benke Hong1

  • 1Department of Natural Product Biosynthesis, Max Planck Institute for Chemical Ecology, Hans-Knöll-Straße 8, Jena 07745, Germany.

Journal of the American Chemical Society
|October 14, 2022
PubMed
まとめ

植物では酸化還元酵素を用いてデヒドロースコーディンを改変し,サイクル添加反応を可能にします. この過程で希少な偽アスピドスペルマアルカロイドが生成され,天然の製品構造の多様性が拡大されます.

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