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Updated: Aug 22, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Sm(II) - プロトン結合電子移転:非常に弱いN-HとO-Hの同解結合強度とそれらを制御する要因の定量化

Emily A Boyd1, Jonas C Peters1

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology (Caltech), Pasadena, California 91125, United States.

Journal of the American Chemical Society
|November 8, 2022
PubMed
まとめ

この研究では,強力な陽子結合電子伝送 (PCET) 反応剤として作用する,明確に定義されたサマリウム (II) 複合体を導入し,特殊な弱いN-HとO-H結合の精密な測定を可能にします.

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