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Updated: Aug 22, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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リモートエナチオセレクティブ [4 + 1] 銅-ビニルビニリデンの中間物質による無効化

Han-Han Kong1, Cuiju Zhu1, Shuang Deng2

  • 1CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, P. R. China.

Journal of the American Chemical Society
|November 11, 2022
PubMed
まとめ

研究者は,イネ-アリルエステルを用いた最初の銅触媒による [4 + 1] 解消を開発した. この方法は,リモートステレオ制御を達成し,高い選択性を持つ多様なスパイロサイクルを生成します.

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