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Updated: Aug 19, 2025

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

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アンビモダルバイスペリサイクル [6 + 4]/[4 + 6] 移行状態 サイクロヘプタトリエンの二極化における二極化経路と競合する:熱二極体の動力学と実験的特徴

Qingyang Zhou1, Mathias K Thøgersen2, Nomaan M Rezayee2

  • 1The College of Chemistry, Nankai University, Tianjin 300071, China.

Journal of the American Chemical Society
|November 28, 2022
PubMed
まとめ

サイクロヘプタトリエンの二酸化は協調された [6 + 4] または段階的なダイラジカル経路で進行し,テトラサイクルの製品を形成する. 温度が支配的な反応機構と産物分布に影響する.

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