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Nuclear Transmutation03:20

Nuclear Transmutation

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Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
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Nuclear Fission02:50

Nuclear Fission

10.0K
Many heavier elements with smaller binding energies per nucleon can decompose into more stable elements that have intermediate mass numbers and larger binding energies per nucleon—that is, mass numbers and binding energies per nucleon that are closer to the “peak” of the binding energy graph near 56. Sometimes neutrons are also produced. This decomposition of a large nucleus into smaller pieces is called fission. The breaking is rather random with the formation of a large...
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Properties of Transition Metals02:58

Properties of Transition Metals

26.8K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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Periodic Classification of the Elements04:00

Periodic Classification of the Elements

46.1K
The periodic table arranges atoms based on increasing atomic number so that elements with the same chemical properties recur periodically. When their electron configurations are added to the table, a periodic recurrence of similar electron configurations in the outer shells of these elements is observed. Because they are in the outer shells of an atom, valence electrons play the most important role in chemical reactions. The outer electrons have the highest energy of the electrons in an atom...
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Other Nuclides: 31P, 19F, 15N NMR01:16

Other Nuclides: 31P, 19F, 15N NMR

436
Many organic, inorganic, and biological molecules contain spin-half nuclei such as nitrogen-15, fluorine-19, and phosphorus-31. As a result, NMR studies of these nuclei have found extensive applications in chemical and biological research.
While fluorine-19 and phosphorous-31 have high natural abundances (100%) and positive gyromagnetic ratios, nitrogen-15 has a low natural abundance and a negative gyromagnetic ratio. However, nitrogen-15 is still preferred over nitrogen-14 (which has a...
436
Nuclear Stability03:18

Nuclear Stability

19.3K
Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together...
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Updated: Aug 16, 2025

Speciation and Bioavailability Measurements of Environmental Plutonium Using Diffusion in Thin Films
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Speciation and Bioavailability Measurements of Environmental Plutonium Using Diffusion in Thin Films

Published on: November 9, 2015

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トランスウラン元素の廃棄物形態の開発: NaMNp6F30 (M = Ti, V, Cr, Mn, Fe, Co, Ni, Al, Ga) の四次性ネプチウムフッ素

Travis K Deason1,2,3, Gregory Morrison1,2, Amir Mofrad1,4

  • 1Center for Hierarchical Waste Form Materials, University of South Carolina, Columbia, South Carolina29208, United States.

Journal of the American Chemical Society
|December 19, 2022
PubMed
まとめ

研究者らは,新型のネプトニウム (IV) フッ素を水熱法で合成した. アクチニド類の同型であるこれらの化合物は,海王星のイオン半径の正確な決定を可能にし,構造的安定性に関する洞察を明らかにした.

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Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles

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関連する実験動画

Last Updated: Aug 16, 2025

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科学分野:

  • 無機化学
  • 固体化学
  • 放射化学

背景:

  • ネプテニウム (IV) フッ素は,核廃棄物の管理とアクティニド化学の理解に不可欠です.
  • 以前の研究は様々なアクティニド化合物に焦点を当てていたが,多様なMサイト元素を持つNp (IV) フッ素の体系的な合成と特徴づけは欠けていた.

研究 の 目的:

  • 一般的な式 Na$_{x}$MNp$_{6}$F$_{30}$を持つ四次性ネプチューニウム{IV) フッ素の一連の合成と特徴付け.
  • ネプチューニウムの四価イオン半径を決定し,他のアクティニドと比較する.
  • これらの化合物とその類似体の構造的安定性と電子的性質を調査する.

主な方法:

  • 軽度の水熱合成により,Np (IV) フッ化物化合物を製造した.
  • 結晶構造と同型関係を決定するために,X線結晶学を用いた.
  • 構造的安定性と電子特性を評価するために,放射線損傷の研究と密度関数理論 (DFT) の計算が行われました.

主要な成果:

  • 一連のNa$_{x}$MNp$_{6}$F$_{30}$化合物 (M = Ti,V,Cr,Mn,Fe,Co,Ni,Al,Ga) が成功して合成されました.
  • 化合物はP-3c1空間群で結晶し,既知のアクチニド類と同型である.
  • ネプチューニウム (1.030(2) Å),プルトニウム (1.014(1) Å),セリウム (1.012(2) Å の正確な四価イオン半径が確立された.
  • 放射線損傷の研究は,構造型の無形化に対する低抵抗を示した.
  • DFT計算は,関連するアクティニド構造の安定性を比較して,バンドギャップと形成のエンタルピーに関する洞察を提供した.

結論:

  • 水熱合成は,新しいネプチューニウム (IV) フッ化物への実行可能な経路を提供します.
  • 確立されたイオン半径は,固体化合物のアクティニド元素の振る舞いをよりよく理解するのに寄与する.
  • 構造のタイプは限られた放射線耐性を表しており,これは潜在的なアプリケーションの重要な考慮事項です.