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Updated: Aug 16, 2025

Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

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メタル・オーガニック・フレームワークにおける負の熱膨張のための調整可能なメカニズムとしてのノード歪み

Zhihengyu Chen1, Gautam D Stroscio2, Jian Liu3

  • 1Department of Chemistry, Stony Brook University, Stony Brook, New York 11794, United States.

Journal of the American Chemical Society
|December 20, 2022
PubMed
まとめ

メタル・オーガニック・フレームワーク (MOF) は,ジルコニウムノードにおける温度による局所的な歪みにより,負の熱膨張 (NTE) を表します. これらのノード歪みをキャピングリガンドで制御することで,MOFのダイナミックな構造と機能を調整する新しい方法が提供されます.

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