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Updated: Aug 14, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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銅超酸化物複合体の形成を通じた酸素強化原子移転基質ポリメリゼーション

Kostas Parkatzidis1, Nghia P Truong1, Richard Whitfield1

  • 1Laboratory of Polymeric Materials, Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 5, Zurich 8093, Switzerland.

Journal of the American Chemical Society
|January 10, 2023
PubMed
まとめ

酸素は,新しいARGET-ATRPメカニズムを通じて,超酸化物種を形成することによって,制御された根性ポリメリゼーションを意外に加速します. この方法はポリメリゼーション率を高め,不純な触媒でも優れた制御を持つ高分子量ポリマーを可能にします.

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