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Updated: Aug 12, 2025

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron

Published on: August 12, 2019

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フォト誘導ニッケル触媒による選択的N-トリアルキラミンの脱メチル化で,HAT反応剤としてC ((sp2) -ブロミドを使用

Xiao Zhang1, Yangyang Shen1, Tomislav Rovis1

  • 1Department of Chemistry, Columbia University, New York, New York 10027, United States.

Journal of the American Chemical Society
|February 1, 2023
PubMed
まとめ

この研究は,光誘導ニッケル触媒とC ((sp2)) -ブロミドを水素原子移転反応剤として使用して,トライキラミンのN-脱メチル化のための軽い,触媒的方法を導入します. このアプローチは,複雑な分子誘導のための広範な機能群互換性とサイト選択性を提供します.

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