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Updated: Aug 10, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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6,6'-ビインデノ[1,2-b]アントラセイン:高度にダイラジカルな開殻ビアリル

Xiushang Xu1,2, Satoshi Takebayashi3, Hiroki Hanayama1

  • 1Organic and Carbon Nanomaterials Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan.

Journal of the American Chemical Society
|February 13, 2023
PubMed
まとめ

研究者らは,新しいオープンシェルビアリル, 6,6′-ビインデノ[1,2-b]アントラゼン (BIA) 誘導体を生成し,高いダイラジカル性を示した. その難解な基本状態は,ほぼ退廃したトリプル状態のシングレットとして識別されました.

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