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Updated: Aug 9, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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カテラニ型反応におけるオルトー制約の解明として機能化されたサイクロオレフィン・リガンド

Feng-Yuan Wang1, Yu-Xiu Li1, Lei Jiao1

  • 1Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University, Beijing 100084, China.

Journal of the American Chemical Society
|February 16, 2023
PubMed
まとめ

この研究は,新しいPd/olefin触媒を用いてCatellani反応の"オルト制限"を克服しています. 設計されたサイクロオレフィンリガンドは,以前は挑戦的なハロアレンを効率的にオルトアルキル化します.

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