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Updated: Aug 7, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
09:22

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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温度感受性共ポリマーを用いた非均衡組成の基本原理の調査

Supraja S Chittari1, Allie C Obermeyer2, Abigail S Knight1

  • 1Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States.

Journal of the American Chemical Society
|March 13, 2023
PubMed
まとめ

合成ポリマーは熱ヒステリシスを示し,組成と加熱/冷却速度に影響される非均衡の振る舞いを示します. この研究は,これらの要因を調整した材料設計に操作することによって,ポリマーの性質を制御する方法を示しています.

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Polymer Classification: Crystallinity

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Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Many natural and synthetic polymers are produced by...
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Characteristics and Nomenclature of Copolymers

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Polymer Classification: Stereospecificity

Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
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