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Updated: Aug 6, 2025

The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
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The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique

Published on: November 28, 2016

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Monosubstituted Doublet Sn(I) 根本的な未消耗軌道角運動を特徴とする

Dongmin Wang1, Wang Chen2,3, Cai Zhai4

  • 1Innovation Center for Chemical Sciences, Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.

Journal of the American Chemical Society
|March 17, 2023
PubMed
まとめ

研究 者 たち は,自由 の 炭酸 素 の 第 一 の 亜鉛 アナログ,中性 の 亜鉛 素 を 合成 し まし た. この新しい化合物は 独特の電子特性と反応性を表し オーガノチン化学の新たな道を開きます

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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks06:53

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride01:26

Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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The allyl systems have identical molecular orbitals but differ in the number of π electrons....
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This lesson delves into the geometry of a radical, which is influenced by the electronic structure of the molecule. The principle is similar to that of a lone pair, where the unpaired electron influences the geometry at the radical center.
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