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Updated: Aug 6, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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イコサヘドラルカルボランのB−H直接機能化水素原子移転

Hongyuan Ren1, Ping Zhang1, Jingkai Xu1

  • 1State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China.

Journal of the American Chemical Society
|March 22, 2023
PubMed
まとめ

研究者は,B-H結合を直接ターゲットにすることで,イコサヘドラルカルボラン (C2B10H12) を機能化するための新しいラジカル媒介方法を開発した. この金属のないアプローチは,カルボラン化学のための新しい経路を提供して,多様な派生を可能にします.

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