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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS

Published on: June 20, 2014

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ダイレクトダイナミクスの軌跡は,Fe-Oxo-Mediated C-H機能化反応中のダイナミックマッチングと非統計的ラジカルペア中間を証明する

Jyothish Joy1, Daniel H Ess1

  • 1Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, United States.

Journal of the American Chemical Society
|March 23, 2023
PubMed
まとめ

非ヘムフェオキソ複合体は,水素原子移転 (HAT) によるC−H結合と反応する. 新しいダイナミクスは,反応の選択性は,単に中間物質ではなく,ダイナミックな効果によって駆動され,C-H機能化の新しいモデルを提供することを明らかにします.

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