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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
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トランスシラクロヘプテンの合成と環開きメタテシスのポリメリゼーションとそのポリマーの単分子力学

Herbert Wakefield1, Ilia Kevlishvili2, Kelsie E Wentz1

  • 1Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218, United States.

Journal of the American Chemical Society
|April 5, 2023
PubMed
まとめ

研究者は新型のストレントサイクロアルケネ,シラサイクロヘプテンを合成した. トランスシラサイクロヘプテンの同位体は,リング開きメタテシスのポリメリゼーションにおいて独特の反応性を示し,分子適合性の高いポリマーを生成した.

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