有機基質と水の酸化において高い反応性を有するマンガン化合物Iモデル

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Updated: Aug 3, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
05:47

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

Published on: August 7, 2018

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Lina Zhang1, Mi Sook Seo1, Yunhee Choi2

  • 1Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea.

Journal of the American Chemical Society
|April 10, 2023
PubMed
まとめ

研究者らは,アルカンの水酸化と水酸化反応を効率的に触媒化する新しいマンガンポルフィリン複合体を合成しました. この非常に反応性の高い化合物は 酸化化学における重要な進歩を表しています

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Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of ManganeseII Acetylacetonate09:02

Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of ManganeseII Acetylacetonate

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Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition10:45

Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition

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Radical Oxidation of Allylic and Benzylic Alcohols01:21

Radical Oxidation of Allylic and Benzylic Alcohols

Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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