海噴霧マイクロドロップレットの空気と水の界面におけるチオールとチオエーターの自発的酸化
Zepeng Rao1, Xiaojiao Li2, Ye-Guang Fang3
1Department of Environmental Science, Zhejiang University, Hangzhou 310058, China.
Journal of the American Chemical Society
|May 3, 2023
まとめ
海洋噴霧エロゾール (SSA) は,光化学反応だけでなく,新たに発見された自発的な経路を通じて有機硫黄の酸化を促進します. このプロセスは地球上の硫黄の循環を加速し,海洋と大気の化学的変化に影響を与えます.
科学分野:
- 環境化学
- 大気化学
- 地化学
背景:
- 溶解した有機硫黄化合物は,チオールやチオエーテルのように,海から大気中に海噴霧エアロゾール (SSA) を介して輸送されます.
- これらの硫黄化合物の酸化は主に光化学的プロセスに起因している.
研究 の 目的:
- SSA内のチオールとチオエッターの非光化学的,自発的な酸化経路を調査し,報告する.
- 主要な酸化製品を特定し,この自発的な酸化を駆動するメカニズムを解明する.
主な方法:
- SSAサンプルにおけるチオール/チオエーテル酸化の分析
- 分析技術を用いた酸化製品の特定
- 空気と水のインタフェースの濃縮と急性生成の役割の調査
主要な成果:
- 自然に豊富に存在する10種のチオール/チオエーテルのうち7種がSSAで急速な酸化を経験した.
- 主要な酸化産物には,二硫化物,硫酸化物,および硫素が含まれます.
- 自発的酸化は,イオン化された種からの界面濃縮と急性形成によって引き起こされる.
結論:
- SSAにおけるチオール/チオエーテルにとって,以前見過ごされていた重要な非光化学的酸化経路が存在する.
- この自発的な酸化は 硫黄の循環を加速します
- この経路は,海洋と大気との接点における水銀循環などの金属変換にも影響を与える可能性があります.
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