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Updated: Jul 31, 2025

Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
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Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy

Published on: February 20, 2020

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ルイス酸補助C ((sp3) -C ((sp3) 黄金における還元性除去

Cyril A Theulier1, Yago García-Rodeja2, Karinne Miqueu2

  • 1CNRS/Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA, UMR 5069), 118 Route de Narbonne, 31062 Cedex 09 Toulouse, France.

Journal of the American Chemical Society
|May 3, 2023
PubMed
まとめ

黄金複合体からエタンの還元性除去を容易にする新しいフォスフィン-ボランリガンド (1-Fxyl). このルイス酸による経路は,ズウィテリオン介質による活性化エネルギーを大幅に低下させ,C−C結合効率を高めます.

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