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Updated: Jul 31, 2025

Gene-therapy Inspired Polycation Coating for Protection of DNA Origami Nanostructures
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DNA安定した銀ナノクラスターの塩化物リガンド

Anna Gonzàlez-Rosell1, Sami Malola2, Rweetuparna Guha1

  • 1Department of Materials Science and Engineering, University of California, Irvine, California 92697, United States.

Journal of the American Chemical Society
|May 8, 2023
PubMed
まとめ

DNA安定した銀ナノクラスター (AgN-DNA) は,塩化物リガンドを組み込み,生物学的条件での安定性を高めることができます. この発見は,バイオフォトニクスにおけるAgN-DNAの構造的多様性と応用を拡大する.

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Metal-Ligand Bonds02:51

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Complexation Equilibria: Factors Influencing Stability of Complexes

In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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Crystal Field Theory
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CFT focuses on...
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