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Updated: Jul 30, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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BF3 - ハリドリサイクルによるアルキンの内分子酸化

E Ali McKnight1, Ramon Arora2, Ekadashi Pradhan1

  • 1Department of Chemistry, York University, Toronto, Ontario M3J 1P3, Canada.

Journal of the American Chemical Society
|May 12, 2023
PubMed
まとめ

三化物 (BF3) 誘導反応は,アルキンをC−F結合に挿入することで,化合物の原子経済的な合成を可能にします. この方法は,高ステレオ選択性を持つ有価な3-[フッ素メチレン]オキシンドールとγ-ラクタムを効率的に生成します.

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