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Updated: Jul 29, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions

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オルトオメティブ [2π + 2σ] サイクルアザアレンの光環添加物

Roman Kleinmans1, Subhabrata Dutta1, Kristers Ozols1

  • 1Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 36, 48149 Münster, Germany.

Journal of the American Chemical Society
|May 26, 2023
PubMed
まとめ

この研究では,N-ヘテロアレンから複雑な3D分子を作るためのオルト選択的光サイクル添加法が導入されています. この新しいストレンスリリースアプローチは,以前の制限を克服して,C ((sp3)) に富んだビサイクロ[2.1.1]ヘクサンを効率的に合成します.

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