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Updated: Jul 28, 2025

Coulomb Explosion Imaging as a Tool to Distinguish Between Stereoisomers
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軌道解像度で追跡C-Hアクティベーション

Raphael M Jay1, Ambar Banerjee1, Torsten Leitner1

  • 1Department of Physics and Astronomy, Uppsala University, 751 20 Uppsala, Sweden.

Science (New York, N.Y.)
|June 1, 2023
PubMed
まとめ

研究者は,ロジウム複合体による炭素-水素 (C-H) 結合の活性化中の電荷移転相互作用を観察するために,高度なX線スペクトロスコピーを用いた. これは,電子の寄付とバックドネーションがC-H活性化を制御し,移行金属の反応性を制御する新しい方法を可能にします.

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