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Updated: Jul 27, 2025

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
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Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR

Published on: December 16, 2013

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非酵素トランスアミネーションにおける金属-ピリドクサルの協力性

Quentin Dherbassy1, Robert J Mayer1, Kamila B Muchowska1

  • 1Université de Strasbourg, CNRS, ISIS & icFRC, 8 Allée Gaspard Monge, 67000 Strasbourg, France.

Journal of the American Chemical Society
|June 6, 2023
PubMed
まとめ

鉄やアルミニウムのような金属イオンは,トランスアミネーション反応におけるコエンザイムであるピリドクスアル (PL) の触媒活性を著しく高めます. これは,酵素が進化する前に,共酵素が触媒的に機能し,初期の生命化学の洞察を提供していたことを示唆している.

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