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Updated: Jul 26, 2025

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BN組み込みサイクロアレン:ワンポットボリレーション合成,光電気特性,ペロブスキート太陽電池での応用

Junting Wang1, Aibin Zheng2, Yuren Xiang2

  • 1Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong 999077, China.

Journal of the American Chemical Society
|June 20, 2023
PubMed
まとめ

研究者らは新型のボロンと窒素 (BN) ドーピングされたサイクロアレンを合成し,最初のBN ドーピングされたヘテロサイクロアレンを作成した. これらの化合物はペロブスキート太陽電池の穴輸送層として有望であり, 14.4%の電力変換効率を達成しています.

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Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
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Pericyclic reactions are organic reactions that occur via a concerted mechanism without generating any intermediates. The reactions proceed through the movement of electrons in a closed loop to form a cyclic transition state, where rearrangement of the σ and π bonds yields specific products.
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