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Updated: Jul 26, 2025

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
09:16

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene

Published on: May 20, 2019

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硫黄とアクリラートのアニオン混合共聚:高性能硫黄ベースのポリマーの合成のための戦略

Hongjun Yang1, Jinfeng Huang1, Yiye Song1

  • 1Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Centre of Photovoltaic Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, P. R. China.

Journal of the American Chemical Society
|June 22, 2023
PubMed
まとめ

研究者らは,アニオンハイブリッドコポリメリゼーションを使用して硫黄ベースのコポリマーを作成するための新しい方法を開発しました. これらの新しいポリマーには 印象的な機械的強度と 室温で自己回復能力があります

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Synthesis of Ligand-free CdS Nanoparticles within a Sulfur Copolymer Matrix

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Anionic Chain-Growth Polymerization: Overview

The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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The carboxylate ion acts as a nucleophile that attacks the carbonyl carbon of the acid chloride to form a tetrahedral intermediate. Subsequently, the re-formation of the carbonyl group with the loss of the chloride ion as a leaving group leads to the formation of an acid...
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Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
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