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Updated: Jul 25, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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カーボキシル誘導体とジハロアルケンのTi-触媒化モジュールケトン合成

Jiabin Ni1, Xiaowen Xia1, Danyu Gu2

  • 1Key Laboratory of Precise Synthesis of Functional Molecules of Zhejiang Province, School of Science, Westlake University, Hangzhou 310024, Zhejiang Province, China; Institute of Natural Sciences, Westlake Institute for Advanced Study, Hangzhou 310024, Zhejiang Province, China.

Journal of the American Chemical Society
|June 26, 2023
PubMed
まとめ

新しいチタン触媒法により,一般的なカルボキシル酸派生物とジェム・ディハロアルカンからケトン合成が可能である. この多用途なプロトコルは,カルボキシル酸の直接オレフィネーションを提供し,機能化されたケトンの合成の可能性を拡大します.

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