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Updated: Jul 24, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

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ニッケルカルボランを添加したBis-N-ヘテロサイクルカルベン

Runxia Nan1,2, Yiwen Li1,2, Zhouli Zhu1,2

  • 1College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, No. 2318, Yuhangtang Road, Hangzhou 311121, Zhejiang China.

Journal of the American Chemical Society
|July 6, 2023
PubMed
まとめ

この研究では,新しいイミダゾリウム機能化されたニッケルカルボランと,ニッケルカルボランを支えるN-ヘテロサイクリックカルベノイド (NHC) に変換する. これらのNHCは,金とセレニウム前駆体と反応し,興味深い電子特性を持つ新しい複合体とアダクトを生成します.

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