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Updated: Jul 22, 2025

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
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A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

Published on: November 12, 2016

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テトラヒドロフランにおけるグリナード反応剤と相互作用するLiClクラスターの形態学的可塑性

Marinella de Giovanetti1, Sondre H Hopen Eliasson1, Abril C Castro1

  • 1Department of Chemistry and Hylleraas Centre for Quantum Molecular Sciences, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo, Norway.

Journal of the American Chemical Society
|July 20, 2023
PubMed
まとめ

テトラヒドロフーラン (THF) 溶液中のリチウム塩化物 (LiCl) は,コンパクトなLi4Cl4アグレガートを形成する. これらの構造は,マグネシウム塩化物 (MgCl2) の存在で分解され,ターボグリナード反応剤に不可欠な,小さな溶解可能な混合Li:Mg:Clクラスターを形成する.

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