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Updated: Jul 22, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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アミノ酸由来イオン性キラル触媒は,遠隔アサイクリック四次性ステレオセンターへの対称性の低下を可能にします

Junqiang Wei1, Vincent Gandon2, Ye Zhu1

  • 1Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.

Journal of the American Chemical Society
|July 20, 2023
PubMed
まとめ

この研究は,遠隔脱対化のための新しいイオン性キラル触媒を導入し,エナチオセレクティブクロスカップリング反応を通じて複雑なキラル分子の生成を可能にします. これらの触媒は,静電方向制御と協調的な相互作用を活用して,精密な長距離ステレオ制御を実現します.

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