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Updated: Jul 21, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

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Z-/Eによるボトルブラッシュポリマーの合成 - 特定の生環開拓メタテシスポリメリゼーション,異なる熱特性を示す

Sirilak Mekcham1, Kotohiro Nomura1

  • 1Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami Osawa, Hachioji, Tokyo 192-0397, Japan.

Journal of the American Chemical Society
|July 27, 2023
PubMed
まとめ

新しいヴァナジウム触媒は,生環開きメタテシスポリメリゼーションを通じて,ボトルブラッシュポリマー (BBPs) のZまたはE選択的合成を可能にし,コポリマーをブロックします. これらのポリマーは,ステレオ化学とサイドチェーンの結晶化に基づいて,異なる性質を示す.

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