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Updated: Jul 17, 2025

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

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二次アルコールとケトンの二次C (sp3) -H結合のイリジウム触媒性サイト選択シリレーション

Jake W Wilson1, Bo Su1, Makoto Yoritate1

  • 1Department of Chemistry, University of California, Berkeley, California 94720, United States.

Journal of the American Chemical Society
|August 28, 2023
PubMed
まとめ

この研究は,アルコールまたはケトンからanti-1,3-diolsを作成するためのイリジウム触媒法を導入します. これは特定のC−H結合のステレオ選択的シリレーションによって達成され,新しい合成経路を可能にします.

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