π

Ryosuke Takehara1,2, Natsuki Kubo1,2, Meguya Ryu3

  • 1Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.

PubMed
まとめ

π スタックされた有機物質の熱輸送は,スタックされた列に沿って,水晶のような振る舞いを示す音響フォノンによって支配されています. 分子内振動からのエネルギーも,このフォノン媒介の熱伝導性に寄与する.

関連する概念動画

Thermal Sigmatropic Reactions: Overview01:16

Thermal Sigmatropic Reactions: Overview

Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in...
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Mechanisms of Heat Transfer II

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Mechanism of heat transfer01:19

Mechanism of heat transfer

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Mechanisms of Heat Transfer01:14

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