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Updated: Jul 15, 2025

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics
13:58

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics

Published on: September 28, 2016

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ペンタゴンか ヘクサゴンか ブリッジか バックミンスターフルレンの表面上の単一のヴァナジウムカチオンの位置を特定する

Jianzhi Xu1, Joost M Bakker2, Olga V Lushchikova2

  • 1MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China.

Journal of the American Chemical Society
|September 27, 2023
PubMed
まとめ

研究者はバクミンスターフルレネC60にバナジウムカチオンの結合位置を特定した. 安定した η5-C60V+複合体は軌道と静電相互作用によって形成され,フルレンの表面化学を明らかにする.

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Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
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